Lithuanian Journal of Physics article / Lietuvos fizikos žurnalo straipsnis

[PDF] http://dx.doi.org/10.3952/lithjphys.46312

Open access article / Atviros prieigos straipsnis

Lith. J. Phys. 46, 283–293 (2006)

Review
ELECTRICAL PROPERTIES OF HYDRATED VANADIUM COMPOUNDS
V. Bondarenka and A. Pašiškevičius
Semiconductor Physics Institute, A. Goštauto 11, LT-01108 Vilnius, Lithuania
E-mail: bond@pfi.lt

Received 15 June 2006

Vanadium pentoxide gels have a layered structure, where V–O ribbons are separated by water that permit to intercalate a wide range of various ionic and molecular species into these gels. They have both ionic and electronic conduction. The ionic part is defined by proton diffusion and the electronic one by the electron hopping between vanadium ions of different valence states.
In this review the results of a complex study concerning the physical properties of a wide range of vanadium based hydrated compounds such as H₂V_12−xMe_xO_31±δ·nH₂O (Me = Mo, Ti, Cr), Me₂V₁₂O_31±δ·nH₂O (Me = Li, Na, K, Rb, Cs), and MeV₁₂O_31±δ·nH₂O (Me = Mg, Ca, Ba) are presented.
The basic attention is given to the description of structure, synthesis, electrical properties, and valence conditions of metal ions in the xerogels.

Keywords: vanadium oxides, hydrates, physical properties
PACS: 73.25.+I, 81.20.Fw, 82.70.Dg

HIDRATUOTŲ VANADŽIO JUNGINIŲ ELEKTRINĖS SAVYBĖS
V. Bondarenka, A. Pašiškevičius
Puslaidininkių fizikos institutas, Vilnius, Lietuva

Vanadžio pentoksido geliai turi sluoksniuotą sandarą, kur V–O sluoksniai atskirti vandens molekulėmis. Tai leidžia įterpti tarp sluoksnių įvairius jonus bei molekules. Elektrinis gelių laidumas turi du sandus – elektroninį, atsirandantį dėl elektronų šuolių tarp įvairiavalenčių jonų, ir protoninį, kurį lemia protonų difuzija.
Pateikti hidratuotų vanadžio junginių, tokių kaip H₂V_12−xMe_xO_31±δ·nH₂O (Me = Mo, Ti, Cr), Me₂V₁₂O_31±δ·nH₂O (Me = Li, Na, K, Rb, Cs) ir MeV₁₂O_31±δ·nH₂O (Me = Mg, Ca, Ba), kompleksinių tyrimų rezultatai.
Pagrindinis dėmesys skirtas hidratų sandaros, sintezės, elektrinių savybių ypatybėms ir metalų jonų valentingumui.

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